ω-Alkenyl-α-methoxy-benzyllithiums : Original synthesis and reactivity

DOI: 10.1016/S0040-4039(97)01411-1

Source and publish data:

Tetrahedron Letters p. 6291 - 6294 (1997)

Update date:2022-08-03

Topics:

Authors:

Krief, Alain

Bousbaa, Jamal

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(97)01411-1

1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce a five or a six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces a five membered cycle possessing the cis-stereochemistry between the methoxy and the adjacent methyl group.

Full text of DOI:10.1016/S0040-4039(97)01411-1

Products guided by the article

Product name:(1-Methoxy-1-methylselanyl-hex-5-enyl)-benzene

Cas No:196607-77-9

R&D Labs maybe for 196607-77-9

Shanghai Xinda Pharmaceuticals Co., Ltd.

Contact:86-21-33692333-8008

Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA

Relevant to this article

Intramolecular [2 + 2] cycloaddition of ketenimines with imines. Synthesis and chemical behaviour of azeto[2,1-b]quinazolines

Doi:10.1016/S0040-4020(97)00855-7
(1997)
Are glycosyl triflates intermediates in the sulfoxide glycosylation method? A chemical and ¹H, ¹³C, and ¹⁹F NMR spectroscopic investigation

Doi:10.1021/ja971239r
(1997)
Decene formation in ethylene trimerization reaction catalyzed by Cr-pyrrole system

Doi:10.1016/j.apcata.2014.01.051
(2014)
The First Total Synthesis of Tricolorin A

Doi:10.1002/anie.199723441
(1997)
On the Reaction between Alkyl Isocyanides and 3-Benzylidene-2,4-pentanedione. A Convenient Synthetic Route to Densely Functionalized Furans

Doi:10.1007/BF00807601
(1997)
Design and synthesis of pyrrolidine-5,5-trans-lactams (5-oxohexahydropyrrolo[3,2-b]pyrroles) as novel mechanism-based inhibitors of human cytomegalovirus protease. 2. Potency and chirality

Doi:10.1021/jm0102203
(2002)

Article Doi