Tetrahedron Letters p. 6291 - 6294 (1997)
Update date:2022-08-03
Topics:
Krief, Alain
Bousbaa, Jamal
1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce a five or a six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces a five membered cycle possessing the cis-stereochemistry between the methoxy and the adjacent methyl group.
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