
Monatshefte fur Chemie p. 697 - 700 (1997)
Update date:2022-08-03
Topics:
Yavari
Shaabani
Maghsoodlou
Alkyl isocyanides undergo a formal (1 + 4] cycloaddition reaction with 3-benzylidene-2,4-pentanedione yielding multiply functionalized furan ring systems in fairly high yields. The 1H NMR spectrum of 4-acetyl -2-(N-benzylamino)-5-methyl-3-pnenylfuran shows an AB pattern for the benzylic methylene protons as a result of a restricted rotation about the bond between the acetyl group and the furan ring, thus giving rise to perpendicular disymmetric planes.
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Doi:10.1039/j39680002060
(1968)Doi:10.1021/ja971829p
(1997)Doi:10.1007/s00706-017-1961-5
(2017)Doi:10.1246/bcsj.40.2715
(1967)Doi:10.1039/a704076h
(1997)Doi:10.1055/s-1997-1029
(1997)