Total enantiotopic discrimination between carbon atoms of a double bond in the reaction of diolates with meso-Bis(phenylsulfonyl)alkenes - Synthesis of enantiopure ketones

DOI: 10.1002/anie.199715041

Source and publish data:

Angewandte Chemie - International Edition in English p. 1504 - 1506 (1997)

Update date:2022-07-29

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Authors:

Cossu Cossu

De Lucchi

Pasetto Pasetto

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Article abstract of DOI:10.1002/anie.199715041

Desymmetrization of bis(phenylsulfonyl)alkenes 1 provides the desired enantiomer of polycyclic ketones rapidly, in high yields and enantiopure 1 is also readily available in multigram quantities.

Full text of DOI:10.1002/anie.199715041

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