Bioscience, Biotechnology and Biochemistry p. 590 - 592 (1998)
Update date:2022-08-03
Topics:
Baba
Iwata
Hamajima
Ikami
Ishida
Hasegawa
Kiso
A convenient synthesis of the sialyl Lewis X (sLe(x)) tetrasaccharide, NeuAc alpha 2-3Gal beta 1-4(Fuc alpha 1-3)GlcNAc (8), as a carbohydrate ligand for selectins is described. The key step is the reaction between NeuAc alpha 2-3GalSMe (5) as a glycosyl donor and the suitably protected Fuc alpha 1-3GlcNAc derivative (4) as the glycosyl acceptor by using dimethyl(methylthio)sulfonium triflate (DMTST) as the promoter.
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Doi:10.1016/S0040-4039(97)01711-5
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(1997)
