Tetrahedron p. 12933 - 12946 (1997)
Update date:2022-08-02
Topics:
Shimizu, Isao
Satake, Akiharu
Yamamoto, Yoshinori
The palladium-catalyzed reduction of various N-arenesulfonylaziridines bearing α,β-unsaturated ester groups with formic acid and the stereochemistry of the reaction products have been investigated in detail.In all cases examined, (Z)-α,β-enoates, (E)-α,β-enoates, and (E)-β,γ-enoates bearing amino functionality at the δ-position were obtained.The formation of these three reduction products was taken as an indication that palladium-catalyzed isomerization occurs to the reduction step.
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