Tetrahedron Letters p. 4285 - 4287 (2002)
Update date:2022-08-05
Topics:
Cai, Dongwei
Larsen, Robert D
Reider, Paul J
By using toluene as a solvent, 3-lithiopyridine can be generated cleanly at -50°C. The addition of various electrophiles affords useful building blocks, such as the 3-pyridine boronic acid in 87% isolated yield.
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