Journal of the Chemical Society. Chemical communications p. 1178 - 1180 (1980)
Update date:2022-08-03
Topics:
Bartok, Mihaly
Molnar, Arpad
Besides yielding 3-ethyl-3-hydroxypentan-2-one (2) and 3-ethylpentan-2-one (4), 3-ethylpentane-2,3-diol (1) is transformed on copper catalysts into 4-methyl-4-hydroxyhexan-3-one (3) and 4-methylhexan-3-one (5), via 1,2-ethyl migration, this being the first experimental observation of 1,2-bond shift isomerization on copper.
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