Tetrahedron Letters p. 2061 - 2064 (1997)
Update date:2022-08-05
Topics:
Taylor, Richard E.
Haley, Jeffrey D.
A synthetic approach to a new class of microtubule-stabilizing natural products is described which employs a macrocyclic olefination strategy to cyclize the 16-membered lactone ring. The C13-C19 thiazole subunit of epothilone A and B is prepared in high enantioselectivity using a catalytic asymmetric allylation reaction.
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Doi:10.1016/S0040-4039(97)10128-9
(1997)Doi:10.1080/07328319708006192
(1997)Doi:10.1021/ic970342e
(1997)Doi:10.1016/S0040-4039(00)75522-5
(1968)Doi:10.1002/ejoc.200300656
(2004)Doi:10.1007/BF00760600
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