Tetrahedron Letters p. 7937 - 7940 (1997)
Update date:2022-08-02
Topics:
Aldabbagh, Fawaz
Bowman, W. Russell
Mann, Emma
Oxidative radical cyclisation using Bu3SnH has been used for the synthesis of [1,2-c]-fused imidazoles and [1,2-a]-fused pyrroles from imidazolecarbaldehydes and acylpyrroles respectively. The intermediate nucleophilic N-alkyl radicals cyclise onto imidazole and pyrrole rings followed by oxidative re-aromatisation.
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