Rhodium-catalyzed hydroformylation of 2-vinyl- and 3-vinyl-1-tosylpyrroles as a convenient synthetic route to the corresponding 2-(1-tosylpyrrolyl)propanals and derivatives

Article abstract of DOI:10.1080/00397919708005459

2-(1-Tosylpyrrolyl)propanals 2a-b were conveniently prepared (70% yield) via rhodium-catalyzed hydroformylation of the corresponding 2-vinyl- and 3-vinyl-1-tosylpyrroles 1a-b and successfully transformed into some new derivatives (50-90% yield).

Full text of DOI:10.1080/00397919708005459

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Synthetic Communications: An
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Rhodium-Catalyzed
Hydroformylation of 2-Vinyl-
and 3-Vinyl-1-tosylpyrroles As
a Convenient Synthetic Route
to the Corresponding 2-(1-
Tosylpyrrolyl)propanals and
Derivatives
Roberta Settambolo a , Aldo Caiazzo b & Raffaello
Lazzaroni b
a Istituto di Chimica Quantistica ed Energetica
Molecolare del CNR , via Risorgimento 35, 56126,
Pisa, Italy
b Centro di Studio del CNR per le Macromolecole
Stereordinate ed Otticamente Attive, Dipartimento
di Chimica e Chimica Industriale , via Risorgimento
35, 56126, Pisa, Italy
Published online: 22 Aug 2006.
To cite this article: Roberta Settambolo , Aldo Caiazzo & Raffaello Lazzaroni (1997)
Rhodium-Catalyzed Hydroformylation of 2-Vinyl- and 3-Vinyl-1-tosylpyrroles As
a Convenient Synthetic Route to the Corresponding 2-(1-Tosylpyrrolyl)propanals
and Derivatives, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 27:23, 4111-4120, DOI:
10.1080/00397919708005459

To link to this article: http://dx.doi.org/10.1080/00397919708005459
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