Synthesis of pseudo-sugars based on desymmetrization of dienylsilanes

DOI: 10.1016/S0040-4039(97)10388-4

Source and publish data:

Tetrahedron Letters p. 8841 - 8844 (1997)

Update date:2022-08-04

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Authors:

Angelaud, Remy

Landais, Yannick

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Article abstract of DOI:10.1016/S0040-4039(97)10388-4

A synthesis of pseudo-sugars using the desymmetrization of a dienylsilane, followed by a stereocontrolled introduction of the hydroxymethyl group at C5, is described. The CH₂OH group at C5 was elaborated using either a regioselective cyclopropane-ring opening or a [2,3]-Wittig rearrangement.

Full text of DOI:10.1016/S0040-4039(97)10388-4

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