Tetrahedron Letters p. 8841 - 8844 (1997)
Update date:2022-08-04
Topics:
Angelaud, Remy
Landais, Yannick
A synthesis of pseudo-sugars using the desymmetrization of a dienylsilane, followed by a stereocontrolled introduction of the hydroxymethyl group at C5, is described. The CH2OH group at C5 was elaborated using either a regioselective cyclopropane-ring opening or a [2,3]-Wittig rearrangement.
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