Diastereoselective formal synthesis of the antifungal agent, (+)- Preussin. A new entry to chiral pyrrolidines

DOI: 10.1016/S0040-4039(97)10468-3

Source and publish data:

Tetrahedron Letters p. 131 - 134 (1998)

Update date:2022-08-04

Topics:

Authors:

Armas, Pedro De

Garcia-Tellado, Fernando

Marrero-Tellado, Jose J.

Robles, Juana

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Article abstract of DOI:10.1016/S0040-4039(97)10468-3

A formal total synthesis of (+)-Preussin was achieved by using D- mannose as the starting material. The key step involved diastereoselective addition of allyltrimethylsilane to the bicyclic ketal 5.

Full text of DOI:10.1016/S0040-4039(97)10468-3

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