Tetrahedron Letters p. 131 - 134 (1998)
Update date:2022-08-04
Topics:
Armas, Pedro De
Garcia-Tellado, Fernando
Marrero-Tellado, Jose J.
Robles, Juana
A formal total synthesis of (+)-Preussin was achieved by using D- mannose as the starting material. The key step involved diastereoselective addition of allyltrimethylsilane to the bicyclic ketal 5.
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