Journal of Organometallic Chemistry p. 421 - 433 (1997)
Update date:2022-07-30
Topics:
Jacob
Voigt
Merzweiler
Pietzsch
[3-(N,N-dimethylaminopropyl]-lithium (DMAP)Li (I) reacts with chloro(triphenylphosphane)-gold(I) ClAu · P(C6H6)3 to form monometallic organo gold(I)-derivate (DMAP)Au · P(C6H5)3 (1) respectively with [2-(dimethylaminomethyl)ferrocenyl]-lithium (FcN)Li (II) to form a heterobimetallic organo gold(I)-compound (FcN)Au · P(C6H5)3 (2). Reactions of the gold(I)-complexes ClAu · P(C6H4F-p)3, ClAu · P(C6H4F)3 and ClAu · P(C6F5)3 with II lead to the formation of (FcN)Au · P(C6H4F-p)3 (3), (FcN)Au ? P(C6H4F-m)3 (4), respectively [FcNAu]2 (5). The platinum(II)-derivatives PtCl2 and cis-Cl2Pt[P(C6H5)3]2 react with II to the heterobimetallic platin organika (FcN)2Pt (6) and (FcN)PtCl · P(C6H5)3 (7). A more detailed characterization of the organo derivatives 1-7 was carried out by elementary analyses, mass-, NMR- and Moessbauer spectroscopy as well as by X-ray crystal structure analyses referring to 2, 5, 6.
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