Rotational features of carbon-nitrogen bonds in axially chiral o-tert- butyl anilides and related molecules. Potential substrates for the 'prochiral auxiliary' approach to asymmetric synthesis

DOI: 10.1016/S0957-4166(97)00599-5

Source and publish data:

Tetrahedron Asymmetry p. 3955 - 3975 (1997)

Update date:2022-07-29

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Authors:

Curran, Dennis P.

Hale, Gregory R.

Geib, Steven J.

Balog, Aaron

Cass, Quezia B.

Degani, Ana Luiza G.

Hernandes, Marcelo Z.

Freitas, Luiz Carlos G.

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Article abstract of DOI:10.1016/S0957-4166(97)00599-5

A new strategy for asymmetric induction termed the 'prochiral auxiliary' approach is introduced. Reactions of acylating agents with prochiral N- methyl-o-tert-butyl aniline provide anilides that are axially chiral by virtue of restricted rotation about th

Full text of DOI:10.1016/S0957-4166(97)00599-5

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