Tetrahedron Letters p. 1637 - 1640 (1998)
Update date:2022-08-03
Topics:
Bartels, Bjoern
Martin, Concepcion Gonzalez
Nelson, Adam
Russell, Matthew G.
Warren, Stuart
Lithium N-benzyl-α-methylbenzylamide adds to prochiral vinyl phosphine oxides in the presence of trimethylsilyl chloride to provide, after protodesilylation, β-amino phosphine oxides as single diastereoisomers. A mechanism which explains the role of trimethylsilyl chloride is proposed.
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