REACTION OF SPIRO WITH GRIGNARD REAGENTS IN THE PRESENCE OF CUPROUS CHLORIDE

DOI: 10.1246/cl.1985.427

Source and publish data:

Chemistry Letters p. 427 - 428 (1985)

Update date:2022-08-03

Topics:

Authors:

Rodriguez, Gonzalo

Benito, Yolanda

Temprano, Fernando

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1985.427

Attack of MeMgI and PhMgBr in toluene on spiro (1) in the presence of Cu2Cl2 gives 2'-substituted spiro in quantitative yields.Also, attack of PhCH2CH2MgBr on 1 in the presence of Cu2Cl2 afforded 2'-phenethyl, 2'-H and 2'-benzyl (or 2'-p-xylyl) derivatives in toluene (or p-xylene) as solvent.

Full text of DOI:10.1246/cl.1985.427

Products guided by the article

Product name:INDOLO(2,3-B)CYCLOHEPTENE

Cas No:2047-89-4

R&D Labs maybe for 2047-89-4

BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
SHIFANG SUHONG CHEMICAL CO.,LTD

Contact:+86-838-2224563

Address:Room 1207 Zongchen Sunshine No.128 Taishan South Road,Deyang City,Sichuan China

Relevant to this article

The Conversion of 4-Anilinoquinazoline- and 3-Aryl-4-imino-3,4-dihydro-quinazoline-2-carbonitriles into Benzo[4,5]imidazo[1,2-c]quinazoline-6-carbonitriles via Oxidative and Nonoxidative C-N Couplings

Doi:10.1021/acs.joc.5b01514
(2015)
Organocatalytic enantioselective michael addition of 4-hydroxycoumarin to α,β-unsaturated ketones: a simple synthesis of warfarin

Doi:10.1002/ejoc.200900831
(2009)
Doi:10.1021/ja01604a033
(1956)
Doi:10.1016/S0022-328X(00)92648-2
(1968)
Diastereoselective Photocyclization of N-(p-(2,4,6-Triisopropylbenzoyl)benzoyl)-L-phenylalanine Methyl Ester in the Solid State

Doi:10.1021/jo980139g
(1998)
Synthesis and biological activity of A-nor-paclitaxel analogues

Doi:10.1016/S0968-0896(97)00035-7
(1997)

Article Doi