(1-Ethoxyvinyl)lithium in the total synthesis of thymine polyoxin C and uracil polyoxin C

DOI: 10.1248/cpb.46.1034

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1034 - 1038 (1998)

Update date:2022-07-29

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Authors:

Akita, Hiroyuki

Uchida, Kimio

Chen, Cheng Yu.

Kato, Keisuke

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Article abstract of DOI:10.1248/cpb.46.1034

A short path synthesis of the ethyl (methyl 2,3-O-isopropylidene-β-D- allofuranosid)uronate (5) and ethyl (methyl 2,3-O-isopropylidene-α-L- talofuranosid)uronate (6) from methyl 2,3-O-isopropylidene-β-D- ribopentodialdo-1,4-furanoside (3) using (1-ethoxyvinyl)lithium and its application to the total synthesis of the pyrimidine nucleosides, thymine polyoxin C (1) and uracil polyoxin C (2), are described.

Full text of DOI:10.1248/cpb.46.1034

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