Tetrahedron Letters p. 2149 - 2152 (1998)
Update date:2022-08-03
Topics:
Aoyagi, Sakae
Hasegawa, Yoko
Hirashima, Shintaro
Kibayashi, Chihiro
A new practical route for the first total synthesis of (+)- homopumiliotoxin 223G is described, in which the palladium-catalyzed carbonylation of the vinyl iodide, leading to efficient construction of the quinolizidine nucleus incorporating the (Z)-alkylidene side chain, is the key strategic clement. Another key feature of this synthesis involves the Lewis acid-induced chelation-controlled propargylation using the allenylsilane with complete diastereoselectivity.
View MoreZibo Linzi Darong Fine Chemical Co., Ltd(expird)
Contact:86-532-67773200; 15689126900
Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Contact:86-379-63338609
Address:Jiudian Village,Deting Town,Song County,Luoyang
Zipont chem(wuhan）Tech co.，Ltd
Contact:+86-27-87587198
Address:wuhan
Liaoyang Xinyou Chemical Products Co.,Ltd.
Contact:+86-419-5165433 13604191870
Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Doi:10.1021/acschemneuro.6b00297
(2017)Doi:10.1016/S0040-4039(01)97954-7
(1970)Doi:10.1016/j.ica.2019.05.030
(2019)Doi:10.1016/S0040-4020(98)00175-6
(1998)Doi:10.1016/S0040-4039(97)01411-1
(1997)Doi:10.1016/j.poly.2020.114421
(2020)
