Tetrahedron Letters p. 2149 - 2152 (1998)
Update date:2022-08-03
Topics:
Aoyagi, Sakae
Hasegawa, Yoko
Hirashima, Shintaro
Kibayashi, Chihiro
A new practical route for the first total synthesis of (+)- homopumiliotoxin 223G is described, in which the palladium-catalyzed carbonylation of the vinyl iodide, leading to efficient construction of the quinolizidine nucleus incorporating the (Z)-alkylidene side chain, is the key strategic clement. Another key feature of this synthesis involves the Lewis acid-induced chelation-controlled propargylation using the allenylsilane with complete diastereoselectivity.
View MoreSINO Industries Company Limited(expird)
Contact:86-29-85369724
Address:No.111, Jiefang Road, Xi’an, China
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd
Contact:+86-771-2311266
Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD
Contact:+86-571-88932183
Address:Hangzhou
Shanghai Bosman Industrial Co., Ltd
Contact:86-21-63065878-8006
Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
Doi:10.1021/acschemneuro.6b00297
(2017)Doi:10.1016/S0040-4039(01)97954-7
(1970)Doi:10.1016/j.ica.2019.05.030
(2019)Doi:10.1016/S0040-4020(98)00175-6
(1998)Doi:10.1016/S0040-4039(97)01411-1
(1997)Doi:10.1016/j.poly.2020.114421
(2020)
