Synthesis and electrode properties of 16-membered azo- and azoxycrown ethers. Structure of tribenzo-16-azocrown-6

DOI: 10.1016/S0040-4020(98)00203-8

Source and publish data:

Tetrahedron p. 4977 - 4990 (1998)

Update date:2022-08-03

Topics:

Authors:

Luboch, Elzbieta

Biernat, Jan F.

Simonov, Yurii A.

Dvorkin Dvorkin

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Article abstract of DOI:10.1016/S0040-4020(98)00203-8

16-Membered benzoazo- and benzoazoxycrown ethers have been synthesized by reductive macrocyclization of respective bis(nitrophenoxy)oxaalkanes. The isomers of azocrown ethers were separated and E and Z structures were ascribed. Behavior of the compounds as ionophores in ion-selective membrane electrodes has been studied. Structure of Z isomer of 16-membered tribenzoazocrown ether has been determined.

Full text of DOI:10.1016/S0040-4020(98)00203-8

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