Tetrahedron p. 4977 - 4990 (1998)
Update date:2022-08-03
Topics:
Luboch, Elzbieta
Biernat, Jan F.
Simonov, Yurii A.
Dvorkin
16-Membered benzoazo- and benzoazoxycrown ethers have been synthesized by reductive macrocyclization of respective bis(nitrophenoxy)oxaalkanes. The isomers of azocrown ethers were separated and E and Z structures were ascribed. Behavior of the compounds as ionophores in ion-selective membrane electrodes has been studied. Structure of Z isomer of 16-membered tribenzoazocrown ether has been determined.
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