Selectivity in the Rearrangement of a Di(pyrrolylmethyl)-2H-pyrrole

DOI: 10.1039/c39870001313

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1313 - 1315 (1987)

Update date:2022-08-03

Topics:

Authors:

Hawker, Craig J.

Stark, W. Marshall

Battersby, Alan R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001313

A di(pyrrolylmethyl)-2H-pyrrole has been synthesised and its ready acid-catalysed rearrangement shows that one of the two possible modes of cleavage is preferred; this mode corresponds to that required for the formation of uroporphyrinogen-III from the putative spiro intermediate.

Full text of DOI:10.1039/c39870001313

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:9-Benzyloxycarbonyl-4-[5-benzyloxycarbonyl-3-(2-methoxycarbonylethyl)-4-(methoxycarbonylmethyl)pyrrol-2-ylmethyl]-2,8-bis(2-methoxycarbonylethyl)-3,7-bis(methoxycarbonylmethyl)-4,5-dihydodipyrrin-1(10H)-one

Cas No:207971-37-7

R&D Labs maybe for 207971-37-7

Suzhou Sibian Chemical Technology Co., Ltd

website:http://www.sibianpharm.com

Contact:+8618169181984,+8618013186906

Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
henan victory industry co.ltd

Contact:86-371-63655023

Address:No.85,jinshui road,zhengzhou,China
Nanjing lanbai chemical Co.,Ltd.

Contact:+86-25-85499326

Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province

Relevant to this article

Doi:10.1111/j.1365-2621.2000.tb10263.x
(1905)
Synthesis of 5′-terminal capped oligonucleotides using O-N phosphoryl migration of phosphoramidite derivatives

Doi:10.1021/ol2026075
(2012)
5-Chloro-N-(4-methoxy-3-piperazin-1-yl-phenyl)-3-methyl-2- benzothiophenesulfonamide (SB-271046): A potent, selective, and orally bioavailable 5-HT₆ receptor antagonist [1]

Doi:10.1021/jm980532e
(1999)
Synthesis of polycyclic lactams and sultams by a cascade ring-closure metathesis/isomerization and subsequent radical cyclization

Doi:10.1055/s-2005-862386
(2005)
Doi:10.1016/0040-4020(72)80121-2
(1972)
Intramolecular epoxidation of unsaturated oxaziridines

Doi:10.1055/s-1998-1733
(1998)

Article Doi