Selectivity in the Rearrangement of a Di(pyrrolylmethyl)-2H-pyrrole

DOI: 10.1039/c39870001313

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1313 - 1315 (1987)

Update date:2022-08-03

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Authors:

Hawker, Craig J.

Stark, W. Marshall

Battersby, Alan R.

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Article abstract of DOI:10.1039/c39870001313

A di(pyrrolylmethyl)-2H-pyrrole has been synthesised and its ready acid-catalysed rearrangement shows that one of the two possible modes of cleavage is preferred; this mode corresponds to that required for the formation of uroporphyrinogen-III from the putative spiro intermediate.

Full text of DOI:10.1039/c39870001313

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