α-Fluorination of methyl phenyl sulfoxide and related compounds by molecular fluorine: A novel method for the introduction of fluorine into sulfoxides bearing α-H atoms

DOI: 10.1248/cpb.44.703

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 703 - 708 (1996)

Update date:2022-08-03

Topics:

Authors:

Toyota, Akemi

Ono, Yoshinori

Chiba, Jun

Sugihara, Takumichi

Kaneko, Chikara

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.44.703

Direct formation of α-fluorosulfones from sulfoxides bearing α-H atoms merely by reaction with molecular fluorine (5% F₂/N₂) is reported, and a novel non-Pummerer-type mechanism is proposed for this α-fluorination reaction.

Full text of DOI:10.1248/cpb.44.703

NII-Electronic Library Service

Products guided by the article

Product name:ethyl 2-fluoro-2-(phenylsulfonyl)acetate

Cas No:20808-13-3

R&D Labs maybe for 20808-13-3

Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Chengdu ZY Biochemical Technology Co., LTD

Contact:0086-28-88680086

Address:170 Qingpu Road, Shouan Town, Pujiang County
Zouping Fuhai Technology Development Co., Ltd.

Contact:+0532-86934525 18660293207

Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Guangzhou Probig Fine Chemical Co., Ltd.

Contact:020-86297874

Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin

Relevant to this article

SAR analysis of adenosine diphosphate (hydroxymethyl)pyrrolidinediol inhibition of poly(ADP-ribose) glycohydrolase

Doi:10.1021/jm020541u
(2003)
Asymmetric synthesis of a key ring a synthon for 1α-hydroxy-19-nor vitamin D

Doi:10.1016/S0040-4039(98)00682-0
(1998)
Synthesis of the nonproteinogenic amino acid (2s,3s,4s)-3-hydroxy-4- methylproline, a constituent of echinocandins

Doi:10.1016/S0957-4166(98)00112-8
(1998)
Stereoselective synthesis of oxygenated trisubstituted olefins using N-ylides [2,3]rearrangement

Doi:10.1055/s-1998-1745
(1998)
Mild N-dealkylation of tertiary, benzylic amines with acid chlorides: Application to solid-phase chemistry

Doi:10.1016/S0040-4039(98)00584-X
(1998)
Enantioselective synthesis of (S)-2-hydroxypropanone derivatives by benzoylformate decarboxylase catalyzed C-C bond formation

Doi:10.1002/1099-0690(200006)2000:11<2161::AID-EJOC2161>3.0.CO;2-6
(2000)

Article Doi