α-Fluorination of methyl phenyl sulfoxide and related compounds by molecular fluorine: A novel method for the introduction of fluorine into sulfoxides bearing α-H atoms

DOI: 10.1248/cpb.44.703

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 703 - 708 (1996)

Update date:2022-08-03

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Authors:

Toyota, Akemi

Ono, Yoshinori

Chiba, Jun

Sugihara, Takumichi

Kaneko, Chikara

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Article abstract of DOI:10.1248/cpb.44.703

Direct formation of α-fluorosulfones from sulfoxides bearing α-H atoms merely by reaction with molecular fluorine (5% F₂/N₂) is reported, and a novel non-Pummerer-type mechanism is proposed for this α-fluorination reaction.

Full text of DOI:10.1248/cpb.44.703

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