Synthesis and reactivity of dendrimers based on phosphoryl (P=O) groups

Article abstract of DOI:10.1080/10426509708044195

The synthesis of phosphoryl-based dendrimers is described, using the reiteration of a two-steps process which gives alternatively aldehyde and P(O)Cl₂ end groups. The synthesis has been carried out up to the third generation, to give a compound which bears 24 chlorine atoms on the surface. Preliminary experiments on the first generation of the dendrimer possessing either 6 CHO or 6 Cl groups show that these compounds display a versatile reactivity. For instance, α, β-unsaturated esters, crown ethers, chiral phosphine sulfides or diallylamine are grafted on the surface, and the resulting dendrimers are isolated in good to nearly quantitative yields.

Full text of DOI:10.1080/10426509708044195

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Phosphorus, Sulfur, and Silicon and the
Related Elements
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SYNTHESIS AND REACTIVITY OF
DENDRIMERS BASed ON PHOSPHORYL (P=O)
GROUPS
Marie-Laure Lartigue a , Anne-Marie Caminade a & Jean Pierre Majoral a
a Laboratoire de chimie de Coordination du , CNRS , 205 route e
Narbonne, 31077, TOULOUSE Cedex 4, France
Published online: 04 Oct 2006.
To cite this article: Marie-Laure Lartigue , Anne-Marie Caminade & Jean Pierre Majoral (1997) SYNTHESIS
AND REACTIVITY OF DENDRIMERS BASed ON PHOSPHORYL (P=O) GROUPS, Phosphorus, Sulfur, and Silicon
and the Related Elements, 123:1, 21-34, DOI: 10.1080/10426509708044195
To link to this article: http://dx.doi.org/10.1080/10426509708044195
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