General syntheses of ethyl 2-ulosonates and 3-deoxy-D-manno-oct-2- ulosonic acid from carbohydrate lactones with 1-ethoxyvinyllithium

DOI: 10.1016/S0040-4039(98)00590-5

Source and publish data:

Tetrahedron Letters p. 3809 - 3812 (1998)

Update date:2022-09-26

Topics:

Authors:

Jiang, Shende

Rycroft, Anthony D.

Singh, Gurdial

Wang, Xiang-Zhu

Wu, Yu-Lin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00590-5

Reactions of 1-ethoxyvinyllithium with isopropylidene or benzyl protected sugar lactones afforded the corresponding hemiacetals which, on ozonolysis, gave the ethyl 2-ulosonates. This allowed a rapid and efficient synthesis of 3-deoxy-D-manno-oct-2-ulosonic acrid (KDO).

Full text of DOI:10.1016/S0040-4039(98)00590-5

Products guided by the article

Product name:(3aS,6R,6aS)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-4-(1-ethoxy-vinyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-ol

Cas No:209125-57-5

R&D Labs maybe for 209125-57-5

Sdow

website:http://www.sdowchem.com

Contact:86-135-2193 7483

Address:8-106 taiyue building
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd

Contact:+86-0372-3662335 +86-0372-3661988

Address:hanling industrial park anyang
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China

Relevant to this article

Chemically Induced Degradation of Sirtuin 2 (Sirt2) by a Proteolysis Targeting Chimera (PROTAC) Based on Sirtuin Rearranging Ligands (SirReals)

Doi:10.1021/acs.jmedchem.6b01872
(2018)
Diels-Alder reactions of (R(s))-3-[(1S)-isoborneol-10-sulfinyl]- 1- methoxybuta-1,3-dienes with electron-deficient carbodienophiles. The effects of Lewis acid catalysis

Doi:10.1016/S0957-4166(98)00138-4
(1998)
Precise control of RNA cleavage by ribozyme mimics

Doi:10.1039/a800818c
(1998)
Deprotonation of calixarenes in acetonitrile

Doi:10.1021/jo051312t
(2005)
The use of Cu and Zn salicylaldimine complexes as catalyst precursors in ring opening polymerization of lactides: Ligand effects on polymer characteristics

Doi:10.1002/aoc.1728
(2011)
Doi:10.1016/S0040-4039(00)75551-1
(1968)

Article Doi