Synthesis, structure and properties of new pyridylaminophosphine complexes

Article abstract of DOI:10.1080/10426509708545662

Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.

Full text of DOI:10.1080/10426509708545662

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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Synthesis, Structure
and Properties of New
Pyridylaminophosphine
Complexes
Stephen M. Aucott , Alexandra M. Z. Slawin & J.
Derek Woollins
a Department of Chemistry , Loughborough
University , Loughborough, Leics, UK, LE11 3TU
b Department of Chemistry , Loughborough
University , Loughborough, Leics, UK, LE11 3TU
c Department of Chemistry , Loughborough
University , Loughborough, Leics, UK, LE11 3TU
Published online: 02 Apr 2008.
To cite this article: Stephen M. Aucott , Alexandra M. Z. Slawin &
J. Derek Woollins (1997) Synthesis, Structure and Properties of New
Pyridylaminophosphine Complexes, Phosphorus, Sulfur, and Silicon and the
Related Elements, 124:1, 473-476, DOI: 10.1080/10426509708545662
To link to this article: http://dx.doi.org/10.1080/10426509708545662
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