Tetrahedron p. 7765 - 7776 (1998)
Update date:2022-07-29
Topics:
Joseph, Benoit
Cornec, Olivier
Merour, Jean-Yves
An intramolecular Heck reaction was performed with palladium(II) acetate on iodoethylenic esters 6-7 to afford an ethylenic seven-membered system 8- 9. α-alkylation of 8 was investigated to afford the corresponding α-methyl compound 10. This new family of compounds 11-12 gave access to potential antiinflammatory agents.
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