A novel and chiral synthesis of both enantiomers of trans-3-amino-4- hydroxyhexahydroazepine, a key intermediate for the synthesis of balanol

DOI: 10.1248/cpb.44.624

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 624 - 626 (1996)

Update date:2022-07-30

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Authors:

Naito Naito

Torieda Torieda

Tajiri Tajiri

Ninomiya

Kiguchi Kiguchi

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Article abstract of DOI:10.1248/cpb.44.624

Both enantiomers of the hexahydroazepine (7), key intermediates for the synthesis of (-)-balanol (1) and its enantiomer, were effectively synthesized via the shortest route involving stannyl radical cyclization of the aldehyde (4) connected with oxime eth

Full text of DOI:10.1248/cpb.44.624

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