A novel and chiral synthesis of both enantiomers of trans-3-amino-4- hydroxyhexahydroazepine, a key intermediate for the synthesis of balanol

DOI: 10.1248/cpb.44.624

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 624 - 626 (1996)

Update date:2022-07-30

Topics:

Authors:

Naito Naito

Torieda Torieda

Tajiri Tajiri

Ninomiya

Kiguchi Kiguchi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.44.624

Both enantiomers of the hexahydroazepine (7), key intermediates for the synthesis of (-)-balanol (1) and its enantiomer, were effectively synthesized via the shortest route involving stannyl radical cyclization of the aldehyde (4) connected with oxime eth

Full text of DOI:10.1248/cpb.44.624

NII-Electronic Library Service

Products guided by the article

Product name:(4-Hydroxy-butylamino)-acetaldehyde O-benzyl-oxime

Cas No:210752-10-6

R&D Labs maybe for 210752-10-6

Huludao Tianqi Shengye Chemical Co.,Ltd.

Contact:0086 429 2075777

Address:Area B,Shipbuilding Industry Park,Beigang District,Huludao City,Liaoning prov.,China
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
ZiBO KuoDing Trade company Ltd

website:http://www.sdzbkd.com

Contact:86-13361591822

Address:GongQingTuan road

Relevant to this article

The stereoselectivity of inhibition of rat liver mitochondrial MAO-A and MAO-B by the enantiomers of 2-phenylpropylamine and their derivatives

Doi:10.1016/S0223-5234(99)80080-4
(1999)
Alkyneselenolate vs Selenoketenyl Coordination: Synthesis and reactivity of [Ir(SeC≡CC₆H₄Me-4)(CO)(PPh₃)₂]

Doi:10.1021/om980268n
(1998)
Iron(0)-Catalyzed Transfer Hydrogenative Condensation of Nitroarenes with Alcohols: A Straightforward Approach to Benzoxazoles, Benzothiazoles, and Benzimidazoles

Doi:10.1021/acs.joc.0c02191
(2020)
Trichloromethylative Olefin Cycloamination by Photoredox Catalysis

Doi:10.1002/ejoc.202100898
(2021)
Purin-6-One Derivatives as Phosphodiesterase-2 Inhibitors

Doi:10.1155/2016/6878353
(2016)
Asymmetric synthesis and antiviral activities of L-carbocyclic 2',3'- didehydro-2',3'-dideoxy and 2',3'-dideoxy nucleosides

Doi:10.1021/jm9901327
(1999)

Article Doi