Towards polyketide libraries - II: Synthesis of chiral aracemic DI- and triketides on a solid support

DOI: 10.1016/S0040-4039(98)00924-1

Source and publish data:

Tetrahedron Letters p. 4801 - 4804 (1998)

Update date:2022-08-03

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Authors:

Reggelin, Michael

Brenig, Volker

Welcker, Reinhard

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Article abstract of DOI:10.1016/S0040-4039(98)00924-1

A new fluoride ion cleavable linker serves as starter unit for iterative asymmetric aldol reactions on a solid support. The synthetic protocol relies on the boron enolate chemistry of D. A. Evans and a cyclic reestablishment of key functionalities. It entails the opportunity for the generation of di- and triketide libraries.

Full text of DOI:10.1016/S0040-4039(98)00924-1

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