Nitroalkenes as precursors to the aromatic spiroketal skeleton of γ- rubromycin. A Nef-type reaction mediated by Pearlman's catalyst

DOI: 10.1016/S0040-4039(98)01046-6

Source and publish data:

Tetrahedron Letters p. 5429 - 5432 (1998)

Update date:2022-08-05

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Authors:

Capecchi, Tanya

De Koning, Charles B.

Michael, Joseph P.

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Article abstract of DOI:10.1016/S0040-4039(98)01046-6

The first synthesis of the benzannelated spiroketal core of γ- rubromycin using Henry condensations and a novel Nef-type reaction induced by Pearlman's catalyst is described.

Full text of DOI:10.1016/S0040-4039(98)01046-6

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