Protonation of fischer-type alkylidyne carbonyltungsten complexes. Structural comparison of alkylidyne and alkylidene metal complexes, including a neutron diffraction study of [W(CHCH3)Cl2(CO) (PMe3)2]

DOI: 10.1016/S0020-1693(98)00004-8

Source and publish data:

Inorganica Chimica Acta p. 7 - 23 (1998)

Update date:2022-07-29

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Authors:

Bastos, Cecilia M.

Lee, Ken S.

Kjelsberg, Michael A.

Mayr, Andreas

Van Engen, Donna

Koch, Stephen A.

Franolic, John D.

Klooster, Wim T.

Koetzle, Thomas F.

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Article abstract of DOI:10.1016/S0020-1693(98)00004-8

Protonation of alkylidyne tungsten complexes of the types [W(CR)Cl(CO)(PMe₃)₃] or [W(CR)Cl(CO)(py)(PMe₃)₂] with HCl affords the η²-alkylidene tungsten complexes [W(CHR)Cl₂(CO)(PMe_{3
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Full text of DOI:10.1016/S0020-1693(98)00004-8

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Product name:WCl(CO)(PMe₃)2(CNC₆H₃Me₂-2,6)(CPh)

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