p-Cyano substituted 5-benzoyldeoxyuridine as a novel electron-accepting nucleobase for one-electron oxidation of DNA

DOI: 10.1016/S0040-4039(98)01231-3

Source and publish data:

Tetrahedron Letters p. 5995 - 5998 (1998)

Update date:2022-08-05

Topics:

Authors:

Nakatani, Kazuhiko

Fujisawa, Kazuhiko

Dohno, Chikara

Nakamura, Takashi

Saito, Isao

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Article abstract of DOI:10.1016/S0040-4039(98)01231-3

p-Cyano substituted 5-benzoyl-2'-deoxyuridine 1 was synthesized as a novel electron accepting nucleobase. DNA cleavage by 1 under photoirradiation conditions occurred selectively at the 5'-G of 5'GG3' sequences after hot piperidine treatment. Photoirradia

Full text of DOI:10.1016/S0040-4039(98)01231-3

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