Tetrahedron Letters p. 6237 - 6240 (1998)
Update date:2022-08-02
Topics:
Hikage, Naotsuka
Furukawa, Hironori
Takao, Ken-ichi
Kobayashi, Susumu
An advanced intermediate for the heterocyclic aminal core of zoanthamine/norzoanthamine alkaloids was prepared in an enantio and stereoselective manner. Contiguous quaternary chiral centers were selectively constructed utilizing a stereoselective cuprate addition to the readily available (+)-Wieland-Miescher ketone.
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