Synthetic studies of zoanthamine/norzoanthamine alkaloids: Advanced intermediate for the heterocyclic aminal core

DOI: 10.1016/S0040-4039(98)01284-2

Source and publish data:

Tetrahedron Letters p. 6237 - 6240 (1998)

Update date:2022-08-02

Topics:

Authors:

Hikage, Naotsuka

Furukawa, Hironori

Takao, Ken-ichi

Kobayashi, Susumu

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Article abstract of DOI:10.1016/S0040-4039(98)01284-2

An advanced intermediate for the heterocyclic aminal core of zoanthamine/norzoanthamine alkaloids was prepared in an enantio and stereoselective manner. Contiguous quaternary chiral centers were selectively constructed utilizing a stereoselective cuprate addition to the readily available (+)-Wieland-Miescher ketone.

Full text of DOI:10.1016/S0040-4039(98)01284-2

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