Towards the total synthesis of phorboxazoles A and B: Stereocontrolled synthesis of a C20-C32 subunit

DOI: 10.1016/S0040-4039(98)01539-1

Source and publish data:

Tetrahedron Letters p. 7185 - 7188 (1998)

Update date:2022-08-02

Topics:

Authors:

Paterson, Ian

Arnott, Euan A.

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Article abstract of DOI:10.1016/S0040-4039(98)01539-1

The C₂₀-C₃₂ phorboxazole subunit 4, containing 5 stereocentres, was prepared in 8 steps (34%) from ethyl ketone (S)-7. Key steps included a boron-mediated anti aldol reaction and an intramolecular hetero-michael reaction. Installatio

Full text of DOI:10.1016/S0040-4039(98)01539-1

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