
Tetrahedron Letters p. 7005 - 7008 (1998)
Update date:2022-07-29
Topics:
Crimmins, Michael T.
Carroll, Charlotte A.
Wells, Angela J.
A pinacol-type rearrangement of intramolecular photocycloadducts has been accomplished by exploiting a novel ester protecting group that can be easilyremoved from a hindered alcohol. The ester is removed by an intramolecular lactonization, overcoming the steric factors normally associated with pivalate esters.
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