Pinacol-type rearrangements of intramolecular photocycloadducts: Application of the 2,2-dimethyl-4-pentenoate protecting group

DOI: 10.1016/S0040-4039(98)01465-8

Source and publish data:

Tetrahedron Letters p. 7005 - 7008 (1998)

Update date:2022-07-29

Topics:

Authors:

Crimmins, Michael T.

Carroll, Charlotte A.

Wells, Angela J.

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Article abstract of DOI:10.1016/S0040-4039(98)01465-8

A pinacol-type rearrangement of intramolecular photocycloadducts has been accomplished by exploiting a novel ester protecting group that can be easilyremoved from a hindered alcohol. The ester is removed by an intramolecular lactonization, overcoming the steric factors normally associated with pivalate esters.

Full text of DOI:10.1016/S0040-4039(98)01465-8

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