A synthesis of 1-azaanthraquinones via Diels-Alder reaction of 4- hydroxy- and 4-methoxy-2-phenylquinolinequinones with 3-trimethylsilyloxy- 1,3-butadienes: Observation of inverse regioselectivity

DOI: 10.1248/cpb.46.1356

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1356 - 1363 (1998)

Update date:2022-07-30

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Authors:

Horiguchi, Yoshie

Toeda, Akio

Tomoda, Katuhiro

Suzuki, Hideki

Sano, Takehiro

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Article abstract of DOI:10.1248/cpb.46.1356

Diels-Alder reaction of 4-hydroxy-2-phenylquinolinequinone (10a) and 4- methoxy-2-phenylquinolinequinone (10b) with 1-methoxy-3- trimethylsilyloxybutadiene proceeded in a highly regio- and stereoselective manner to give the [4+2] adducts (11) and (14) in

Full text of DOI:10.1248/cpb.46.1356

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