Electronic substituent effects for the fine-tuning of the regioselectivity in the diastereoselective rearrangement of 1,3- cyclopentanediyl radical cations generated from tricyclo[3.3.0.02,4]octanes (housanes) by chemical electron transfer

DOI: 10.1021/ja982329e

Source and publish data:

Journal of the American Chemical Society p. 11858 - 11863 (1998)

Update date:2022-08-04

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Authors:

Adam, Waldemar

Heidenfelder, Thomas

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Article abstract of DOI:10.1021/ja982329e

1,3-Cyclopentanediyl radical cations 5·⁺ were generated from tricyclo[3.3.0.0^2,4]octanes (housanes) 5 through chemical oxidation with tris(4-bromophenyl)aminium hexachloroantimonate (TBA·⁺SbCl₆^-) and

Full text of DOI:10.1021/ja982329e

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