Chemical and Pharmaceutical Bulletin p. 1660 - 1661 (1998)
Update date:2022-08-04
Topics:
Takeya, Tetsuya
Kajiyama, Manabu
Nakamura, Chikara
Tobinaga, Seisho
The first total synthesis of plumbazeylanone (1), which is a trimer of naphthoquinone, was carried out successfully utilizing the unsymmetrical methylene-bridged dimer with the naphthoquinone unit and the naphthol unit, 11b as a key intermediate in 11 steps. This synthesis features a regioselective nucleophilic 1,2-addition reaction and dienone-phenol-type rearrangement.
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Doi:10.1021/jacs.1c04112
(2021)Doi:10.1139/v96-007
(1996)Doi:10.1246/cl.1996.179
(1996)Doi:10.1016/S0040-4039(03)01204-8
(2003)Doi:10.1016/S0040-4039(00)94218-7
(1983)Doi:10.1039/a805478i
(1998)
