Electron Transfer and Chemiluminescence. Two Inefficient Systems: 1,4-Dimethoxy-9,10-diphenylanthracene Peroxide and Diphenoyl Peroxide

DOI: 10.1021/ja00189a043

Source and publish data:

Journal of the American Chemical Society p. 2633 - 2639 (1989)

Update date:2022-08-03

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Authors:

Catalani, Luiz H.

Wilson, Therese

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Article abstract of DOI:10.1021/ja00189a043

The 1,4-endoperoxide of 1,4-dimethoxy-9,10-diphenylanthracene (1) rearranges under mild acidic conditions to the 1,2-dioxetane 3, which has been characterized by NMR.The decomposition of 3 is catalyzed by fluorescers (such as 1) in a bimolecular process w

Full text of DOI:10.1021/ja00189a043

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