Stereoselective synthesis of an isomer of membrenone-C via an aldol based two directional chain extension

DOI: 10.1016/S0040-4039(98)01846-2

Source and publish data:

Tetrahedron Letters p. 8367 - 8370 (1998)

Update date:2022-07-31

Topics:

Authors:

Perkins, Michael V.

Sampson, Rebecca A.

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Article abstract of DOI:10.1016/S0040-4039(98)01846-2

An isomer of Membrenone-C was prepared in 8 steps (17% yield) with 93% overall ds starting from the ethyl ketone (S)-10. Key steps are the boron- mediated aldol followed by anti selective reduction, giving the C₆-C₁₀ stereochemistry,

Full text of DOI:10.1016/S0040-4039(98)01846-2

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