Cycloadditions of (Arylalkylamino)ketenes with Cycloalkenes

DOI: 10.1021/jo00273a011

Source and publish data:

Journal of Organic Chemistry p. 2834 - 2838 (1989)

Update date:2022-08-02

Topics: Regioselectivity Column chromatography Yield NMR spectroscopy Catalyst Nucleophile Electrophile Mass spectrometry (MS) Diels-Alder Reaction Solvent Effects Stereoselectivity Cycloaddition Staudinger Reaction 1,3-Dipolar Cycloaddition Ketenes Pericyclic reaction Transition state HOMO-LUMO interaction

Authors:

Brady, William T.

Gu, Yi Qi

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Article abstract of DOI:10.1021/jo00273a011

(Arylalkylamino)ketenes were prepared from the corresponding glycine derivatives and underwent in situ cycloadditions with cyclopentadiene, cycloheptene, and cyclooctene to yield only the endo-bicyclocyclobutanones.The cycloheptene and cyclooctene cycload

Full text of DOI:10.1021/jo00273a011

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