Journal of Organic Chemistry p. 2834 - 2838 (1989)
Update date:2022-08-02
Topics: Regioselectivity Column chromatography Yield NMR spectroscopy Catalyst Nucleophile Electrophile Mass spectrometry (MS) Diels-Alder Reaction Solvent Effects Stereoselectivity Cycloaddition Staudinger Reaction 1,3-Dipolar Cycloaddition Ketenes Pericyclic reaction Transition state HOMO-LUMO interaction
Brady, William T.
Gu, Yi Qi
(Arylalkylamino)ketenes were prepared from the corresponding glycine derivatives and underwent in situ cycloadditions with cyclopentadiene, cycloheptene, and cyclooctene to yield only the endo-bicyclocyclobutanones.The cycloheptene and cyclooctene cycload
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