COMPORTEMENT DES ORGANOMAGNESIENS VIS-A-VIS DE COMPOSES ACETYLENIQUES DISUBSTITUES EN PRESENCE DE PdCl2

DOI: 10.1016/S0022-328X(00)83386-0

Source and publish data:

Journal of Organometallic Chemistry p. 1 - 10 (1982)

Update date:2022-09-26

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Authors:

Broquet, C.

Riviere, H.

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Article abstract of DOI:10.1016/S0022-328X(00)83386-0

In the presence of HMPT as a cosolvent, uncomplexed PdCl2 can be used in addition reactions of reducing or non-reducing Grignard reagents with disubstituted acetylenic compounds.Stereospecific conjugated dienes are obtained in good yields together with dialkylation and reduction products.

Full text of DOI:10.1016/S0022-328X(00)83386-0

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