Tetrahedron Letters p. 5409 - 5412 (1988)
Update date:2022-08-03
Topics:
Nakai, Ei-ichi
Nakai, Takeshi
A novel <2,3>Wittig variant, termed "siloxy-<2,3>Wittig rearrangement", has been developed which provides the half-silylated 1,2-diol systems with a high anti-diastereoselectivity.The unusual anti-selectivity is discussed on mechanistic grounds.
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