Chemistry Letters p. 1743 - 1746 (1992)
Update date:2022-08-05
Topics: Synthesis Characterization Crystal engineering Substituent effect Hindered phenols Crystal structure determination
Takagi, Koichi
Mizuno, Akira
Kubata, Michiru
Mizoguchi, Akira
Furushow, Masaru
Matsuoka, Masaru
2,6-di-tert-butylphenol moiety was found to be effective to control molecular packing in crystals for SHG materials.Many derivatives having compact acceptor group at 4-position of hindered phenols showed SHG responses depending on the electron withdrawing effect of an acceptor.The X-ray structural analyses revealed that molecular packing was controlled both by the steric requirements and the intermolecular hydrogen bonding.
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