Studies on macrocyclic diterpenoids (XIX) - Total synthesis of (RR/SS)-sinulariol-B

DOI: 10.1016/0040-4039(95)02276-7

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1996)

Update date:2022-08-05

Topics:

Authors:

Yue Yue

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02276-7

The first total synthesis of (RR/SS)-sinulariol-B (1) was achieved in ten steps and ~ 10% overall yield from E-geraniol (8). The key step was the macrocyclization of precursor 5 by thioether-stabilized carbanionic alkylations.

Full text of DOI:10.1016/0040-4039(95)02276-7

Products guided by the article

Product name:2-((3E,7E,11E)-4,8,12-Trimethyl-2-phenylsulfanyl-cyclotetradeca-3,7,11-trienyl)-1-trimethylsilanyloxy-propan-2-ol

Cas No:220364-44-3

R&D Labs maybe for 220364-44-3

Ningbo Distant Chemicals Co.,Ltd

Contact:86-574-27862490,27862438

Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China

Relevant to this article

Synthesis and evaluation of guanidine-containing schiff base copper(II), zinc(II), and iron(III) chelates as trypsin inhibitors

Doi:10.1248/cpb.51.625
(2003)
Stereoselective synthesis of chiral amino allenes by organocopper- mediated anti-S(N)2'-substitution reaction of chiral ethynylaziridines

Doi:10.1016/S0040-4020(00)00136-8
(2000)
Synthesis, structure and reactivity of the hexaphospha-titanocene, bis-(η⁵-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)titanium(II)

Doi:10.1039/a905469c
(1999)
Asymmetric synthesis of arylglycines and their use as chiral templates for the stereocontrolled synthesis of 7,8-disubstituted 3-Aryl-1,2,3,4-tetrahydroisoquinolin-4-ols

Doi:10.1002/1099-0690(200111)2001:22<4343::AID-EJOC4343>3.0.CO;2-D
(2001)
Preparation and X-ray structure of 4-N,N′-bis(trimethylsilyl)-amino-3,5-diisopropylphenylselenium trichloride

Doi:10.1515/znb-1999-0913
(1999)
A general synthesis of 1-(1-alkenyl)benzotriazoles

Doi:10.1016/S0040-4020(99)00690-0
(1999)

Article Doi