Studies on macrocyclic diterpenoids (XIX) - Total synthesis of (RR/SS)-sinulariol-B

DOI: 10.1016/0040-4039(95)02276-7

Source and publish data:

Tetrahedron Letters p. 671 - 674 (1996)

Update date:2022-08-05

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Authors:

Yue Yue

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Article abstract of DOI:10.1016/0040-4039(95)02276-7

The first total synthesis of (RR/SS)-sinulariol-B (1) was achieved in ten steps and ~ 10% overall yield from E-geraniol (8). The key step was the macrocyclization of precursor 5 by thioether-stabilized carbanionic alkylations.

Full text of DOI:10.1016/0040-4039(95)02276-7

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