Cationic lanthanide alkyl complexes. Evidence for an unprecedented tetraphenylborate coordination mode in La(C5Me5){CH(SiMe3)2}BPh4

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Article abstract of DOI:10.1021/om00046a060

Reaction of La(C₅Me₅){CH(SiMe₃)₂}₂ (1) with [PhNMe₂H]BPh₄ affords zwitterionic La(C₅Me₅){CH-(SiMe₃)₂}BPh ₄ (2a), which reac

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Combining the [2,3] sigmatropic rearrangement and ring-closing metathesis strategies for the synthesis of spirocyclic alkaloids. A short and efficient route to (±)-perhydrohistrionicotoxin

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