Deracemization of anti-1,2-diols leading to trans-epoxides via oxazaborolidine-mediated enantiomer-differentiating ring-cleavage of acetal derivatives

DOI: 10.1016/S0040-4039(98)02387-9

Source and publish data:

Tetrahedron Letters p. 503 - 506 (1999)

Update date:2022-07-29

Topics:

Authors:

Harada, Toshiro

Nakamura, Tomohito

Kinugasa, Motoharu

Oku, Akira

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Article abstract of DOI:10.1016/S0040-4039(98)02387-9

An enantioconvergent transformation of racemic anti-1,2-diols to enantiomerically enriched (71-96% ee) trans-epoxides is realized via chiral oxazaborolidine-mediated enantiomer-differentiating ring-cleavage reaction of the acetal derivatives.

Full text of DOI:10.1016/S0040-4039(98)02387-9

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