SILICON MODIFIED REDUCTION AND REDUCTIVE ALKYLATION - APPLICATION TO THE PHENANTHRENE SYSTEM

DOI: 10.1016/S0040-4039(00)82108-5

Source and publish data:

Tetrahedron Letters p. 3761 - 3764 (1988)

Update date:2022-08-02

Topics:

Authors:

Rabideau, Peter W.

Marcinow, Zbigniew

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Article abstract of DOI:10.1016/S0040-4039(00)82108-5

A trimethylsilyl (TMS) substituent is used to control the metal-ammonia reduction of phenanthrenes.The TMS group is then removed by tetrabutylammonium fluoride (TBAF) and replaced by either H or R'.

Full text of DOI:10.1016/S0040-4039(00)82108-5

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