Bioscience, Biotechnology and Biochemistry p. 424 - 426 (1999)
Update date:2022-08-04
Topics:
Yoshikawa, Hiromichi
The mixed anhydride method was applied to synthesize O-aryl O-ethyl phenylphosphonothionate. The reaction of O, O-diethyl phosphorochloridate with O-ethyl phenylphosphonothioic acid afforded O, O-diethyl phosphoric O-ethyl phenylphosphonothioic anhydride in a good yield. This anhydride was converted to O-aryl O-ethyl phenylphosphonothionates by reacting with the appropriate sodium phenoxide. This esterification occurred without racemization and produced optically pure O-ethyl O-(4-nitrophenyl) phenylphosphonothionate (EPN) and O-(4-cyanophenyl) O-ethyl phenylphosphonothionate (cyanofenphos).
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(1999)Doi:10.1007/BF01031789
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(1999)Doi:10.1016/S0040-4039(01)00298-2
(2001)Doi:10.1016/S0008-6215(98)00287-0
(1998)Doi:10.1021/jo01068a073
(1961)
