Radical-mediated imidoylation of telluroglycosides. Insertion of isonitriles into the glycosidic carbon-tellurium bond

DOI: 10.1016/S0040-4039(99)00183-5

Source and publish data:

Tetrahedron Letters p. 2347 - 2350 (1999)

Update date:2022-07-29

Topics:

Authors:

Yamago, Shigeru

Miyazoe, Hiroshi

Goto, Ryuta

Yoshida, Jun-ichi

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Article abstract of DOI:10.1016/S0040-4039(99)00183-5

Telluroglycosides react with isonitriles under photo-thermal conditions to give 1-telluroimidoylglycosides. The reaction proceeds by atom transfer radical reaction to form an imidic C-Te bond, which can be substituted to a C-C bond and C-O bond under oxidative conditions.

Full text of DOI:10.1016/S0040-4039(99)00183-5

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