Tetrahedron Letters p. 1519 - 1522 (1999)
Update date:2022-08-03
Topics:
Kobayashi, Satoshi
Peng, Ge
Fukuyama, Tohru
Stereocontrolled biomimetic total syntheses of the title compounds are described. Our syntheses feature a highly efficient preparation of the key intermediate 11 using our novel indole synthesis methodology. A novel amine protecting protocol by means of 2,4-dinitrobenzenesulfonamides has been developed to ensure the formation of the elusive secodine (3) as well as secodine-type intermediate (4) under very mild conditions.
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Doi:10.1016/S0040-4039(99)00023-4
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(2015)
