Generation of oxiranyllithiums and oxiranyl Grignard reagents having a carbanion-destabilizing group from sulfinyloxiranes: Their property and an application to asymmetric synthesis of epoxides and alcohols

DOI: 10.1016/S0040-4020(99)00038-1

Source and publish data:

Tetrahedron p. 2515 - 2528 (1999)

Update date:2022-09-26

Topics:

Authors:

Satoh, Tsuyoshi

Kobayashi, Shigeko

Nakanishi, Shino

Horiguchi, Kyoko

Irisa, Shiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(99)00038-1

The first generation of oxiranyllithiums and oxiranyl Grignard reagents having a carbanion-destabilizing group (alkyl group) was realized from sulfinyloxiranes via the ligand exchange reaction of sulfoxides with tert- butyllithium or ethylmagnesium chlori

Full text of DOI:10.1016/S0040-4020(99)00038-1

Products guided by the article

Product name:(2R,R_S)-(+)-1,2-epoxy-1,1-diphenyl-2-(p-tolylsulfinyl)propane

Cas No:223392-15-2

R&D Labs maybe for 223392-15-2

Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA

Relevant to this article

Doi:10.1021/ja01150a045
(1951)
A convergent total synthesis of the macrolactone disaccharide toxin (- )-polycavernoside A

Doi:10.1021/ja990384x
(1999)
Lewis acid-promoted nitroolefination of enol silyl ethers via an addition elimination process

Doi:10.1248/cpb.47.394
(1999)
An M2-V27A channel blocker demonstrates potent in?vitro and in?vivo antiviral activities against amantadine-sensitive and -resistant influenza A viruses

Doi:10.1016/j.antiviral.2017.01.006
(2017)
Carbonyl transposition of α-hydroxyamidals mediated by triphenylphosphine-iodine. A new entry to tetrahydroisoquinolin-4-ones

Doi:10.1016/S0040-4039(98)00535-8
(1998)
Reductive coupling of isatins with ketones and aldehydes by low-valent titanium

Doi:10.1016/j.tet.2014.10.071
(2014)

Article Doi