Generation of oxiranyllithiums and oxiranyl Grignard reagents having a carbanion-destabilizing group from sulfinyloxiranes: Their property and an application to asymmetric synthesis of epoxides and alcohols

DOI: 10.1016/S0040-4020(99)00038-1

Source and publish data:

Tetrahedron p. 2515 - 2528 (1999)

Update date:2022-09-26

Topics:

Authors:

Satoh, Tsuyoshi

Kobayashi, Shigeko

Nakanishi, Shino

Horiguchi, Kyoko

Irisa, Shiro

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Article abstract of DOI:10.1016/S0040-4020(99)00038-1

The first generation of oxiranyllithiums and oxiranyl Grignard reagents having a carbanion-destabilizing group (alkyl group) was realized from sulfinyloxiranes via the ligand exchange reaction of sulfoxides with tert- butyllithium or ethylmagnesium chlori

Full text of DOI:10.1016/S0040-4020(99)00038-1

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